一、个人简介
李泽江,男,副教授,硕士生导师。2015年12月提前毕业并获得兰州大学功能有机分子国家重点实验室有机化学博士学位,导师为柳忠全教授。2016年01月引进并在澳门新葡平台网址8883从事教学与科研工作。迄今为止,在Green Chem.,Org. Lett., Chem. Commun., Adv. Synth. Catal., J. Org. Chem.,等杂志上发表SCI收录论文20余篇,其中一篇工作被评为2014年中国百篇最具影响国际学术论文;先后主持国家自然科学基金、河北省自然科学基金、河北省教育厅基金等多项科研项目。
联系方式:E-mail: lizejiang898@126.com
二、主讲课程及研究方向
1.主讲课程: 有机化学,化学专业英语,基础有机化学实验,有机合成与表征实验等。
2.研究方向: 主要从事绿色有机合成方法学的研究工作;具体研究方向为自由基化学,金属催化。
三、代表性论文
ORCID iD: http://orcid.org/0000-0001-9579-9895
[17] Changyou Guo, Lijun Li,* Qinqin Yan, Hongxun Zhou, Zhong-Quan Liu,* and Zejiang Li*, Photoinduced Tandem Cyanomethylation/Cyclization of Unsaturated Compounds: Access to Cyanomethylated 7- or 5-Membered N-Heterocycles. J. Org. Chem. 2023, 88 (16), 12141-12149.
[16] Yunfei Tian*, Luping Zheng, Yuting Yang, Jiayi Liu, Zihan Jing, Zejiang Li*, Weijun Fu*, Electrochemically Promoted Oxydifluoroethylation of Alkenes for the Synthesis of Difluoroethylated Benzoxazines and Lactones. Adv. Syn. Catal., 2023, 365 (11), 1901-1906.
[15] Yang Li, Lijun Li,* Changyou Guo, Qinqin Yan, Hongxun Zhou, Ying Wang, Zhong-Quan Liu,* and Zejiang Li* Nitro-spirocyclization of biaryl ynones with tert-butyl nitrite: access to NO2-substituted spiro[5,5]trienones J. Org. Chem. 2023, 88 (7), 4854-4862.
[14] Shiliu Chen, Qinqin Yan, Jie Fan, Changyou Guo, Lijun Li, * Zhong-Quan Liu* and Zejiang Li*. Photo-induced spirocyclization of biaryl ynones with ammonium thiocyanate: access to thiocyanate-featured spiro[5,5]trienones Green Chemistry, 2023, 25 (1), 153-160.
[13] Yingming Ren, Qinqin Yan, Yang Li, Yongjun Gao, Jincan Zhao, Lijun Li,* Zhong-Quan Liu,* and Zejiang Li* Free radical-promoted trifluoromethylthiolation of alkynes to access SCF3-containing dibenzazepines or dioxodibenzothiazepines J. Org. Chem. 2022, 87 (13), 8773-8781.
[12] Shiliu Chen, Qinqin Yan, Jie Fan, Yongjun Gao, Xiulong Yang, Lijun Li,* Zhongquan Liu* and Zejiang Li* Photoinduced cascade cyclization of alkynes with NH4SCN: access to SCN-containing dibenzazepines or dioxodibenzothiazepines Green Chemistry, 2022, 24 (12), 4742-4747.(2022 Green Chemistry Hot Articles)
[11] Yingming Ren,§ Yaxin Ge,§ Qinqin Yan, Shiliu Chen, Yang Li, Lijun Li, Zhong-Quan Liu* and Zejiang Li*, Free radical-promoted monochloroalkylarylation of alkenes with chloralkanes J. Org. Chem. 2021, 86 (17), 12460-12466.
[10] Yaxin Ge, Yunfei Tian,* Jilai Wu, Qinqin Yan,* Luping Zheng, Yingming Ren, Jincan Zhao and Zejiang Li* Iron-Promoted Free Radical Cascade Difunctionalization of Unsaturated Benzamides with Silanes Chem. Commun. 2020,56 (83), 12656-12659.
[9] Jilai Wu, Yuanyuan Zong, Chunxia Zhao, Qinqin Yan, Lixian Sun, Yiming Li, Jincan Zhao, Yaxin Ge, Zejiang Li* Silver or cerium-promoted free radical cascade difunctionalization of o-vinylanilides with sodium aryl- or alkylsulfinates Org. Biomol. Chem., 2019, 17 (4), 794-797.
[8] Rui Zhang, Haifei Yu, Zejiang Li*, Qinqin Yan, Pan Li, Jilai Wu, Jing Qi*, Menglu Jiang, Lixian Su, Iron-Mediated Azidomethylation or Azidotrideuteromethylation of Active Alkenes with Azidotrimethylsilane and Dimethyl Sulfoxide Adv. Syn. Catal. 2018, 360 (7), 1384-1388.
[7] Zejiang Li*, Xiaosong Cui, Lin Niu, Yingming Ren, Menghua Bian, Xuebiao Yang, Biao Yang, Qinqin Yan*, Jincan, Zhao, An Iron(II) Chloride-Promoted Radical Cascade Methylation or α-Chloro-β-methylation of N-Arylacrylamides with Dimethyl Sulfoxide Adv. Syn. Catal. 2017, 359 (2), 246-249. (Highlighted by Synfacts)
[6] Zhong-Quan Liu*,Zejiang Li, Radical-promoted site-specific cross dehydrogenative coupling of heterocycles with nitriles Chem. Commun. 2016,52, 14278-14281.
[5] Zejiang Li, Yingxia Xiao, Zhong-Quan Liu*, A radical anti-Markovnikov addition of alkyl nitriles to simple alkenes via selective sp3 C–H bond functionalization Chem. Commun. 2015, 51, 9969-9971.
[4] Zejiang Li, Fenghua Fan, Jie Yang and Zhong-Quan Liu*, A Free Radical Cascade Cyclization of Isocyanides with Simple Alkanes and Alcohols Org. Lett. 2014, 16, 3396-3399.
[3] Zejiang Li, Ye Zhang, Lizhi Zhang and Zhong-Quan Liu*, A Free Radical Cascade Alkylarylation of Alkenes with Simple Alkanes: Highly Efficient Access to Oxindoles via Selective (sp3)C-H and (sp2)C-H Bond Functionalization Org. Lett. 2014, 16, 382-385. 入选2014年中国百篇最具影响国际学术论文。
[2] Zejiang Li, Zili Cui, Zhong-Quan Liu*, Copper- and Iron-Catalyzed Decarboxylative Tri- and Difluoromethylation of r,β-Unsaturated Carboxylic Acids with CF3SO2Na and (CF2HSO2)2Zn via a Radical Process Org. Lett. 2013, 15, 406-409.
[1] Zejiang Li, Yuexia Zhang, Zhong-Quan Liu*, Pd-Catalyzed Olefination of Perfluoroarenes with Allyl Esters Org. Lett. 2012, 14, 74-77.
四、科研项目
1. 单电子诱导氮中心自由基的产生与应用研究(项目批准号:21702044),国家自然科学基金,( 2018.01-2020.12,主持人)。
2. 自由基引发甲基化试剂与丙烯酰胺、异氰、二烯、杂环或芳环的串联关环或偶联反应研究(项目批准号:B2017201043),河北省自然科学基金,(2017.01-2019.12,主持人)。
3. 自由基促进烯烃、炔烃、芳烃(杂环)与亚磺酸钠区域选择性反应(项目批准号:QN2019063),河北省教育厅基金,(2019.01-2021.12,主持人)。
4. 光/电/热作用下氯代烃与烯烃的自由基双官能团化或串联合环反应(项目批准号:B2020201014),河北省自然科学基金,(2020.01-2022.12,主持人)。